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Institute of Theoretical Physics · Faculty of Mathematics and Physics, Charles University

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Article

Molecular Auger Interferometry

M. A. Khokhlova, B. Cooper, K. Ueda, K. C. Prince, P. Kolorenč, M. Yu Ivanov, and V Averbukh

Phys. Rev. Lett. 122(23), 233001 (2019)

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Abstract

We introduce and present a theory of interferometric measurement of a normal Auger decay lifetime in molecules. Molecular Auger interferometry is based on the coherent phase control of Auger dynamics in a two-color (omega/2 omega) laser field. We show that, in contrast to atoms, in oriented molecules of certain point groups the relative omega/2 omega phase modulates the total ionization yield. A simple analytical formula is derived for the extraction of the lifetimes of Auger-active states from a molecular Auger interferogram, circumventing the need in either high-resolution or attosecond spectroscopy. We demonstrate the principle of the interferometric Auger lifetime measurement using inner-valence decay in CH3F.

Institute authors

Supported by

  • GACR 17-10866S — Properties of autoionizing states in atoms, molecules and clusters

BibTeX

@article{UTF807,
  author        = {M. A. Khokhlova, B. Cooper, K. Ueda, K. C. Prince, P. Kolorenč, M. Yu Ivanov, and V Averbukh},
  title         = {{Molecular Auger Interferometry}},
  journal       = {Phys. Rev. Lett.},
  volume        = {122},
  number        = {23},
  pages         = {233001},
  year          = {2019},
  doi           = {http://dx.doi.org/10.1103/PhysRevLett.122.233001},
}